Catalyst Function

A proprietary catalyst enhances hydrogen yield by ~15% in the fixed-bed coal gasification process.

Syngas Composition Impact

H₂ content rises from 40–45 vol% to ~46–52 vol%, improving the H₂/CO ratio (typically at 1.7–2.0 at temperature of 1050–1100°C) ideal for downstream synthesis.

Reaction Enhancement

Promotes water–gas shift and steam reforming, reducing CO, tar, and char, thus improving syngas quality and plant uptime.

Operational Benefits

Enables lower steam-to-oxygen ratio, better thermal balance, and potentially lower operating temperature/pressure.

Economic Outcome

Higher H₂ yield boosts methanol and derivative output per ton of coal; marginal catalyst cost is offset by higher efficiency and reduced downtime.

Overall Result

Delivers cleaner, hydrogen-rich syngas with better process sustainability and energy integration suited to Indian high-ash coal.

Section Reaction / Description Equation
1. Fixed Bed Gasifier Reactions
Partial Oxidation C + ½O₂ → CO
Complete Combustion (minor, for heat) C + O₂ → CO₂
Boudouard Reaction C + CO₂ → 2CO
Water-Gas Reaction C + H₂O → CO + H₂
Methanation C + 2H₂ → CH₄
Water-Gas Shift (in gas phase, equilibrium influenced) CO + H₂O ⇌ CO₂ + H₂
2. Catalyst Column (WGS + Hydrogen Boost)
Water Gas Shift (main reaction) CO + H₂O → CO₂ + H₂
3. Methanol Synthesis Reactor
Primary Reaction CO + 2H₂ → CH₃OH
Secondary Reaction CO₂ + 3H₂ → CH₃OH + H₂O
4. DMEA Synthesis Reactor
Methanol carbonylation (simplified) 2CH₃OH + CO → CH₃OCH₂OCH₃ + H₂O₂
Alternate Route via methylamine
5. Acetic Acid Plant
Methanol carbonylation CH₃OH + CO → CH₃COOH
6. Urea Plant
Urea synthesis 2NH₃ + CO₂ → NH₂CONH₂ + H₂O₂
→ Syngas (from Coal Gasification) Methanol Formaldehyde Polyacetal UF / PF / MF Resins Hexamine Isopropene MDI Polyol MTBE Acetic Acid Vinyl Acetate Monomer Chloromethanes MMA PPMA Methyl Formate Methyl Formamide HCN Methylamines DME Ethanolamines DMF Carbamates Fisher- Tropsch Liquid Fuels Waxes Hydrogen (+ N₂ from Air Sep. Unit) Ammonia Ammonium Nitrate Urea Nitric Acid Hexamine